Sua primeira banda importante foi a Elf, que surgiu em 1965. Nesta banda Ronnie James Dio (nome artístico adotado em homenagem aos parentes italianos) cantava e tocava baixo. Com o fim do conjunto em 1975, Dio aceitou o convite deRitchie Blackomore, que havia deixado o Deep Purple e entrou para o Rainbow. Após uma parceria de grande sucesso, Dio ingressou noBlack Sabbath, onde gravou os clássicosHeaven And Hell (1980) e The Mob Rules(1981), além do ao vivo Live Evil (1982). Dio deixou o Black Sabbath em 1983 devido à problemas pessoais com Tony Iommi, que apelidou Dio de "O Pequeno Hitler".

 Holy Diver - 1983

01 - Stand Up And Shout
02 - Holy Diver
03 - Gypsy
04 - Caught In The Middle
05 - Don't Talk To Strangers
06 - Straight Through The Heart
07 - Invisible
08 - Rainbow In The Dark
09 - Shame On The Night

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 The Last In Line - 1984

01 - We Rock
02 - The Last In Line
03 - Breathless
04 - I Speed At Night
05 - One Night In The City
06 - Evil Eyes
07 - Mystery
08 - Eat Your Heart Out
09 - Egypt (The Chains Are On)

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 Sacred Heart - 1985

01 - King Of Rock And Roll
02 - Sacred Heart
03 - Another Lie
04 - Rock 'N' Roll Children
05 - Hungry For Heaven
06 - Like The Beat Of A Heart
07 - Just Another Day
08 - Fallen Angels
09 - Shoot Shoot

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 Intermision - 1986

01 - King Of Rock And Roll
02 - Rainbow In The Dark
03 - Sacred Heart
04 - Time To Burn
05 - Rock 'N' Roll Children
06 - We Rock

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 Dream Evil - 1987

01 - Night People
02 - Dream Evil
03 - Sunset Superman
04 - All The Fools Sailed Away
05 - Naked In The Rain
06 - Overlove
07 - I Could Have Been A Dreamer
08 - Faces In The Window
09 - When A Woman Cries

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 Lock Up The Wolves - 1990

01 - Wild One
02 - Born On The Sun
03 - Hey Angel
04 - Between Two Hearts
05 - Night Music
06 - Lock Up The Wolves
07 - Evil On Queen Street
08 - Walk On Water
09 - Twisted
10 - Why Are They Watching Me
11 - My Eyes

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 Diamonds - The Best Of Dio - 1992

01 - Holy Diver
02 - Rainbow In The Dark
03 - Don't Talk To Strangers
04 - We Rock
05 - The Last In Line
06 - Evil Eyes
07 - Rock 'N' Roll Children
08 - Sacred Heart
09 - Hungry For Heaven
10 - Hide In The Rainbow
11 - Dream Evil
12 - Wild One
13 - Lock Up The Wolves

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 Strange Highways - 1994

01 - Jesus, Mary And The Holy Ghost
02 - Firehead
03 - Strange Highways
04 - Hollywood Black
05 - Evilution
06 - Pain
07 - One Foot In The Grave
08 - Give Her The Gun
09 - Blood From A Stone
10 - Here's To You
11 - Bring Down The Rain

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 Angry Machines - 1996

01 - Institutional Man
02 - Don't Tell The Kids
03 - Black
04 - Hunter Of The Heart
05 - Stay Out Of My Mind
06 - Big Sister
07 - Double Monday
08 - Golden Rules
09 - Dying In America
10 - This Is Your Life

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 Anthology - 1997

01 - Holy Diver
02 - Rainbow In The Dark
03 - Stand Up And Shout
04 - Straight Through The Heart
05 - Last In Line
06 - One Night In The City
07 - We Rock
08 - Egypt (The Chains Are On)
09 - Shoot Shoot
10 - Time To Burn
11 - All The Fools Sailed Away
12 - I Could Have Been A Dreamer
13 - Sunset Superman
14 - Shame On The Night

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 Inferno - Last In Live - 1998

CD 1:
01 - Intro
02 - Jesus, Mary And The Holy Ghost
03 - Straight Through The Heart
04 - Don't Talk To Strangers
05 - Holy Diver
06 - Drum Solo
07 - Heaven And Hell
08 - Double Monday
09 - Stand Up And Shout
10 - Hunter Of The Heart

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CD 2:
01 - Mistreated (Catch The Rainbow)
02 - Guitar Solo
03 - The Last In Line
04 - Rainbow In The Dark
05 - The Mob Rules
06 - Man On The Silver Mountain
07 - Long Live Rock And Roll
08 - We Rock
09 - After All (The Dead)

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 Master Series - 1998

01 - We Rock
02 - Rock 'N' Roll Children
03 - Why Are They Watching Me
04 - I Could Have Been A Dreamer
05 - Mystery
06 - Just Another Day
07 - Twisted
08 - Last In Line
09 - Fallen Angels
10 - Stand Up And Shout
11 - All The Fools Sailed Away
12 - Night Music
13 - Another Lie
14 - Night People
15 - Hey Angel
16 - Overlove
17 - Like The Beat Of A Heart
18 - Walk On Water

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 Magica - 2000

01 - Discovery
02 - Magica Theme
03 - Lord Of The Last Day
04 - Fever Dreams
05 - Turn To Stone
06 - Feed My Head
07 - Eriel
08 - Challis
09 - As Long As It's Not About Love
10 - Otherworld
11 - Magica (Reprise)
12 - Lord Of The Last Day (Reprise)
13 - Magica Story

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 Anthology - Volume Two - 2001

01 - Don't Talk To Strangers
02 - Gypsy
03 - Invisible
04 - Evil Eyes
05 - Mystery
06 - Rock 'N' Roll Children
07 - Hungry For Heaven
08 - Dream Evil
09 - Naked In The Rain
10 - Hey Angel
11 - Between Two Hearts
12 - Lock Up The Wolves
13 - Rainbow In The Dark (Live)
14 - Long Live Rock And Roll (Live)
15 - We Rock (Live)

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 Killing The Dragon - 2002

01 - Killing The Dragon
02 - Along Comes A Spider
03 - Scream
04 - Better In The Dark
05 - Rock & Roll
06 - Push
07 - Guilty
08 - Throw Away Children
09 - Before The Fall
10 - Cold Feet

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 Stand Up And Shout - The Dio Anthology - 2003

01 - Hoochie Koochie Lady
02 - I'm Coming Back For You
03 - Carolina Country Ball
04 - Man On The Silver Mountain
05 - Starstruck
06 - Long Live Rock 'N' Roll
07 - Neon Knights
08 - Children Of The Sea
09 - Heaven And Hell
10 - Turn Up The Night
11 - The Sign Of The Southern Cross
12 - The Mob Rules
13 - Computer God
14 - Voodoo (Live 1982)

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 The Collection - 2003

01 - Holy Diver
02 - Don't Talk To Strangers
03 - Rainbow In The Dark
04 - Stand Up And Shout (Live)
05 - Straight Through The Heart
06 - We Rock
07 - The Last In Line (Live)
08 - Mystery
09 - I Speed At Night
10 - Rock 'N' Roll Children
11 - Hungry For Heaven
12 - King Of Rock And Roll
13 - Sacred Heart (Live)
14 - Dream Evil
15 - Sunset Superman
16 - I Could Have Been A Dreamer
17 - Wild One
18 - Jesus, Mary And The Holy Ghost

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 Master Of The Moon - 2004

01 - One More For The Road
02 - Master Of The Moon
03 - The End Of The World
04 - Shivers
05 - The Man Who Would Be King
06 - The Eyes
07 - Living The Lie
08 - I Am
09 - Death By Love
10 - In Dreams
11 - Prisoner Of Paradise

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 Evil Or Divine - Live In New York City - 2005

01 - Killing The Dragon
02 - Egypt - Children Of The Sea
03 - Push
04 - Stand Up And Shout
05 - Rock And Roll
06 - Don't Talk To Strangers
07 - Man On The Silver Mountain
08 - Guitar Solo
09 - Long Live Rock And Roll
10 - Fever Dreams
11 - Holy Diver
12 - Heaven And Hell
13 - The Last In Line
14 - Rainbow In The Dark
15 - We Rock

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 Holy Diver Live - 2006

CD 1:
01 - Stand Up And Shout
02 - Holy Diver
03 - Gypsy
04 - Caught In The Middle
05 - Don't Talk To Strangers
06 - Straight Through The Heart
07 - Invisible
08 - Rainbow In The Dark
09 - Shame On The Night

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CD 2:
01 - Tarot Woman
02 - Sign Of The Southern Cross
03 - One Night In The City
04 - Gates Of Babylon
05 - Heaven And Hell
06 - Man On The Silver Mountain
07 - Long Live Rock 'N' Roll
08 - We Rock

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 At Donington UK - Live 1983 & 1987 - 2010

CD 1 - 1983:
01 - Stand Up And Shout
02 - Straight Through The Heart
03 - Children Of The Sea
04 - Rainbow In The Dark
05 - Holy Diver
06 - Drum Solo
07 - Stargazer
08 - Guitar Solo
09 - Heaven & Hell
10 - Man On The Silver Mountain
11 - Starstruck
12 - Man On The Silver Mountain (Reprise)

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CD 2 - 1987:
01 - Dream Evil
02 - Neon Knights
03 - Naked In The Rain
04 - Rock ‘n’ Roll Children
05 - Long Live Rock ‘n’ Roll
06 - The Last In Line
07 - Children Of The Sea
08 - Holy Diver
09 - Heaven & Hell
10 - Man On The Silver Mountain
11 - All The Fools Sailed Away
12 - The Last In Line (Reprise)
13 - Rainbow In The Dark

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 Finding The Sacred Heart: Live In Philly 1986 (Live) (2013)